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Strontium and silicate co-substituted hydroxyapatite: Mechanochemical synthesis and structural characterization Full article

Journal Materials Science and Engineering B: Solid-State Materials for Advanced Technology
ISSN: 0921-5107
Output data Year: 2020, Volume: 262, Pages: 114719 Pages count : 1 DOI: 10.1016/j.mseb.2020.114719
Tags Co–substituted hydroxyapatite; Crystal structure; Mechanochemical synthesis; Silicate; Strontium
Authors Bulina Natalia V. 1,2 , Chaikina Marina V. 1 , Prosanov Igor Yu. 1 , Dudina Dina V. 1,2,3
Affiliations
1 Institute of Solid State Chemistry and Mechanochemistry SB RAS
2 Novosibirsk State University
3 Lavrentyev Institute of Hydrodynamics SB RAS

Abstract: Synthetic hydroxyapatite is a bioceramic material promising for medical applications. The introduction of substituents into the crystal structure of hydroxyapatite allows tailoring its properties and obtaining materials with improved implantation characteristics. In the present work, it was shown for the first time that silicate and strontium co-substituted hydroxyapatite can be synthesized via the “soft” mechanochemical method. The synthesis was carried out by subjecting the reaction mixture to ball milling in the absence of any organic surfactant or solvent. The product of the mechanochemical synthesis was a single-phase material with a nanocrystalline structure. The crystal structure of co-substituted hydroxyapatite Ca9.5Sr0.5(PO4)5.5(SiO4)0.5(OH)1.5 was analyzed for the first time. The synthesized co-substituted hydroxyapatite does not require any further processing or treatment and can be used as a biomaterial in the as-synthesized state.
Cite: Bulina N.V. , Chaikina M.V. , Prosanov I.Y. , Dudina D.V.
Strontium and silicate co-substituted hydroxyapatite: Mechanochemical synthesis and structural characterization
Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020. V.262. P.114719. DOI: 10.1016/j.mseb.2020.114719 WOS Scopus РИНЦ OpenAlex
Identifiers:
Web of science: WOS:000588335900005
Scopus: 2-s2.0-85089949585
Elibrary: 45338151
OpenAlex: W3082608865
Citing:
DB Citing
Scopus 25
OpenAlex 27
Elibrary 22
Web of science 23
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