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Feasible domain of cycling operating conditions and model parameters for Holby–Morgan model of platinum catalyst degradation in PEMFC Full article

Journal International Journal of Hydrogen Energy
ISSN: 0360-3199
Output data Year: 2024, Volume: 51, Number: Part C, Pages: 1518-1526 Pages count : 9 DOI: 10.1016/j.ijhydene.2023.11.182
Tags PROTON-EXCHANGE MEMBRANE FUEL CELL, CATALYST DEGRADATION, PLATINUM DISSOLUTION AND OXIDATION, ACCELERATED STRESS TEST, SENSITIVITY ANALYSIS, FEASIBLE REGION
Authors Kovtunenko Victor Anatolʹevich 1,2
Affiliations
1 Lavrentyev Institute of Hydrodynamics
2 University of Graz

Funding (1)

1 Министерство науки и высшего образования Российской Федерации FWGG-2021-0010

Abstract: In the paper, electrochemical behavior of platinum based cathode catalyst in a polymer electrolyte membrane fuel cell is studied under non-symmetric square-wave electric potential cycling applied in accelerated stress test. Following the modeling by Holby and Morgan, degradation due to Pt dissolution, ion diffusion, and oxide coverage is performed with respect to cycling operating conditions and model parameters. The computer simulation demonstrates impact of the electrochemical surface area loss rate under variation of the temperature, pH, platinum particle diameter, loading, Pt to Carbon volume fraction, and their simultaneous effect. From physical consistency and multi-parametric sensitivity analysis, a statement on feasible domain of the parameters for the PEMFC operation is concluded.
Cite: Kovtunenko V.A.
Feasible domain of cycling operating conditions and model parameters for Holby–Morgan model of platinum catalyst degradation in PEMFC
International Journal of Hydrogen Energy. 2024. V.51. NPart C. P.1518-1526. DOI: 10.1016/j.ijhydene.2023.11.182 WOS Scopus РИНЦ OpenAlex
Dates:
Submitted: May 5, 2023
Accepted: Nov 15, 2023
Published print: Jan 31, 2024
Identifiers:
Web of science: WOS:001137983600001
Scopus: 2-s2.0-85177816040
Elibrary: 60871963
OpenAlex: W4388835353
Citing:
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OpenAlex 5
Elibrary 4
Scopus 5
Web of science 5
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