Fabrication of High-Entropy Alloys Using a Combination of Detonation Spraying and Spark Plasma Sintering: A Case Study Using the Al-Fe-Co-Ni-Cu System Full article
| Journal |
Metals
ISSN: 2075-4701 |
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| Output data | Year: 2023, Volume: 13, Number: 9, Article number : 1519, Pages count : DOI: 10.3390/met13091519 | ||||
| Tags | high-entropy alloy; detonation spraying; spark plasma sintering; hardness; microstructure | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Министерство науки и высшего образования Российской Федерации | FWGG-2021-0005 |
Abstract:
The use of pre-alloyed powders as high-entropy alloy (HEA) coating precursors ensures a predetermined (unaltered) elemental composition of the coating with regard to the feedstock powder. At the same time, it is interesting to tackle a more challenging task: to form alloy coatings
from powder blends (not previously alloyed). The powder-blend-based route of coating formation eliminates the need to use atomization or ball milling equipment for powder preparation and allows for the introduction of additives into the material in a flexible manner. In this work, for the first time, a HEA was obtained using detonation spraying (DS) followed by spark plasma sintering (SPS). A powder mixture with a nominal composition of 10Al-22.5Fe-22.5Co-22.5Ni-22.5Cu (at.%) was detonation-sprayed to form a multicomponent metallic coating on a steel substrate. The elemental composition of the deposited layer was (9 ± 1)Al-(10 ± 1)Fe-(20 ± 1)Co-(34 ± 1)Ni-(27 ± 1)Cu (at.%), which is different from that of the feedstock powder because of the differences in the deposition efficiencies of the metals during DS. Despite the compositional deviations, the deposited layer was still suitable as a precursor for a HEA with a configurational entropy of ~1.5R, where R is the universal
gas constant. The subsequent SPS treatment of the substrate/coating assembly was carried out at 800–1000 ◦C at a uniaxial pressure of 40 MPa. The SPS treatment of the deposited layer at 1000 ◦C for 20 min was sufficient to produce an alloy with a single-phase face-centered cubic structure and a porosity of <1%. Interestingly, the hardness values of the as-sprayed and SPS-treated coatings were close to each other (~320 HV0.3). The hardness of the coatings measured in two perpendicular directions did not differ significantly. The features of the DS–SPS route of the formation of HEA coatings and its potential applications are discussed.
Cite:
Batraev I.S.
, Ulianitsky V.
, Shtertser A.A.
, Dudina D.V.
, Ivanyuk K.V.
, Kvashnin V.I.
, Lukʹyanov Y.L.
, Samodurova M.N.
, Trofimov E.A.
Fabrication of High-Entropy Alloys Using a Combination of Detonation Spraying and Spark Plasma Sintering: A Case Study Using the Al-Fe-Co-Ni-Cu System
Metals. 2023. V.13. N9. 1519 . DOI: 10.3390/met13091519 WOS Scopus РИНЦ OpenAlex
Fabrication of High-Entropy Alloys Using a Combination of Detonation Spraying and Spark Plasma Sintering: A Case Study Using the Al-Fe-Co-Ni-Cu System
Metals. 2023. V.13. N9. 1519 . DOI: 10.3390/met13091519 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Aug 8, 2023 |
| Accepted: | Aug 24, 2023 |
| Published online: | Aug 26, 2023 |
Identifiers:
| Web of science: | WOS:001076280000001 |
| Scopus: | 2-s2.0-85172793174 |
| Elibrary: | 59936576 |
| OpenAlex: | W4386238742 |